Who went

Exodus 13:21
And the LORD went before them in a pillar of cloud to guide their way by day, and in a pillar of fire to give them light at night, so that they could travel by day or night.

Numbers 10:33
So they set out on a three-day journey from the mountain of the LORD, with the ark of the covenant of the LORD traveling ahead of them for those three days to seek a resting place for them.

Psalm 77:20
You led Your people like a flock by the hand of Moses and Aaron.

Ezekiel 20:6
On that day I swore to them to bring them out of Egypt into a land that I had searched out for them, a land flowing with milk and honey, the glory of all lands.

in fire

Exodus 13:21, 22
And the LORD went before them in a pillar of cloud to guide their way by day, and in a pillar of fire to give them light at night, so that they could travel by day or night. . . .

Exodus 14:19, 20, 24
Then the Angel of God, who had gone before the camp of Israel, withdrew and went behind them. The pillar of cloud also moved from before them and stood behind them, . . .

Exodus 40:34-38
Then the cloud covered the Tent of Meeting, and the glory of the LORD filled the tabernacle. . . .

Numbers 9:15-22
On the day that the tabernacle, the Tent of the Testimony, was set up, the cloud covered it and appeared like fire above the tabernacle from evening until morning. . . .

Numbers 10:11, 12
On the twentieth day of the second month of the second year, the cloud was lifted from above the tabernacle of the Testimony, . . .

Numbers 14:14
And they will tell it to the inhabitants of this land. They have already heard that You, O LORD, are in the midst of this people, that You, O LORD, have been seen face to face, that Your cloud stands over them, and that You go before them in a pillar of cloud by day and a pillar of fire by night.

Nehemiah 9:12
You led them with a pillar of cloud by day, and a pillar of fire by night, to light for them the way which they should travel.

Psalm 78:14
He led them with a cloud by day and with a light of fire all night.

Psalm 105:39
He spread a cloud as a covering and a fire to light up the night.

Isaiah 4:5, 6
Then the LORD will create over all of Mount Zion and over her assemblies a cloud of smoke by day and a glowing flame of fire by night. For over all the glory there will be a canopy, . . .

Zechariah 2:5
For I will be a wall of fire around it, declares the LORD, and I will be the glory within it.'"